https://scholars.lib.ntu.edu.tw/handle/123456789/61157
標題: | Visible-light response Cr-doped TiO2-XNX photocatalysts | 作者: | Pan, Chien-Cheng Wu, Jeffrey C.S. |
關鍵字: | Photocatalyst;Sol–gel;Titania;Cr and N doping | 公開日期: | 2006 | 出版社: | Taipei:National Taiwan University Dept Chem Engn | 卷: | 100 | 期: | 1 | 起(迄)頁: | 102-107 | 來源出版物: | Materials Chemistry and Physics | 摘要: | Chromium (Cr) and nitrogen (N)-doped titania (TiO2) was prepared using sol–gel method and ammonia thermal treatment. TiO2 co-doped with Cr and N showed intense absorption bands in the visible-light region. The X-ray photoelectron spectroscopy (XPS) detected chromium and nitrogen ions on the surface of catalysts, but no diffractive peak of chromium oxide or titanium nitride was observed in X-ray diffraction (XRD) spectra. The analysis of X-ray absorption near edge spectroscopy (XANES) indicated either Cr3+ or Cr4+ chemical status implying that chromium either substituted Ti4+ site or locally was isolated on the surface of TiO2. The photocatalytic activity was evaluated by the degradation of methylene blue (MB) and isopropyl alcohol (IPA) under visible-light (>460 nm) irradiation using blue-light emitted diode. The rate constants of MB and IPA photodegradation with N-doped TiO2 were 7.7 and 80 mol l−1 h−1 g−1, which were much higher than those with pure TiO2, 0.15 and 0 mol l−1 h−1 g−1, respectively. The Cr and N co-doped TiO2 showed less photoactivity than either Cr or N-doped TiO2 due to the extra imperfection of TiO2 lattice during preparation. |
URI: | http://ntur.lib.ntu.edu.tw//handle/246246/2006111501243943 | 其他識別: | 246246/2006111501243943 | DOI: | 10.1016/j.matchemphys.2005.12.013 |
顯示於: | 化學工程學系 |
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