https://scholars.lib.ntu.edu.tw/handle/123456789/612100| Title: | Metal-Free Transfer Hydrogenation Catalysis by B(C6F5)(3) | Authors: | Farrell, Jeffrey M. Heiden, Zachariah M. Stephan, Douglas W. JEFFREY M. FARRELL |
Issue Date: | 2011 | Journal Volume: | 30 | Journal Issue: | 17 | Start page/Pages: | 4497-4500 | Source: | ORGANOMETALLICS | Abstract: | The activation of amines by B(C6F5)3 is shown to effect the catalytic racemization of a chiral amine. Extending this strategy to a bimolecular process, catalytic transfer hydrogenation of imines, enamines, and N-heterocycles is demonstrated using iPr2NH as the source of hydrogen and a catalytic amount of the Lewis acid B(C 6F5)3. ? 2011 American Chemical Society. |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-80052438966&doi=10.1021%2fom2005832&partnerID=40&md5=679903e72efd49d694b52a4f46ec93b6 https://scholars.lib.ntu.edu.tw/handle/123456789/612100 |
DOI: | 10.1021/om2005832 | metadata.dc.subject.other: | Bimolecular process; Catalytic amounts; Catalytic transfer hydrogenation; Chiral amines; Enamines; Lewis Acid; N-heterocycles; TO effect; Transfer hydrogenations; Amines; Hydrogenation |
| Appears in Collections: | 化學系 |
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