https://scholars.lib.ntu.edu.tw/handle/123456789/61273
標題: | Vapor-liquid equilibrium of carbon dioxide with diethyl methylmalonate diethyl ethylmalonate and diethyl n-butylmalonate at elevated pressures | 作者: | Hwu, Wen-Hong Cheng, Cheng-His Tang1, Muoi Chen, Yan-Ping |
關鍵字: | vapor-liquid equilibrium;binary mixture;data;carbon dioxide;esters | 公開日期: | 2004 | 出版社: | Taipei:National Taiwan University Dept Chem Engn | 起(迄)頁: | - | 來源出版物: | Fluid Phase Equilibria | 摘要: | Vapor–liquid equilibrium (VLE) data for binary mixtures of CO2 with homologous esters of diethyl methylmalonate, diethyl ethylmalonate, and diethyl n-butylmalonate at 308.2, 318.2, and 328.2 K, respectively, over the pressure range 1.4–8.4MPa were measured using a semi-flow apparatus. New gas solubility data for CO2 in esters are presented, and the Henry’s law constants for CO2 in these esters are evaluated by employing the Krichevsky–Ilinskaya (KI) equation. The VLE data were also correlated using the Soave–Redlich–Kwong and the Peng–Robinson equations of state (EOSs) with various types of mixing rules. It is shown that EOS with both the van der Waals mixing rules and the two adjustable parameters yield satisfactory correlation results. |
URI: | http://ntur.lib.ntu.edu.tw//handle/246246/2006111501233105 | 其他識別: | 246246/2006111501233105 |
顯示於: | 化學工程學系 |
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