https://scholars.lib.ntu.edu.tw/handle/123456789/627621
DC Field | Value | Language |
---|---|---|
dc.contributor.author | SHENG-DER CHAO | en_US |
dc.date.accessioned | 2023-02-03T09:23:13Z | - |
dc.date.available | 2023-02-03T09:23:13Z | - |
dc.date.issued | 2022 | - |
dc.identifier.issn | 0009-4536 | - |
dc.identifier.uri | https://scholars.lib.ntu.edu.tw/handle/123456789/627621 | - |
dc.description.abstract | Molecules in high Rydberg states, or high Rydberg molecules, are special types of excited species. Classically, at least one of the valence electrons of such molecules is excited to a high-energy near-threshold orbit with a negative eccentricity. Therefore, the electron spends most of its orbiting time on roaming slowly far away from the parent ionic core. With this classical picture in mind, we develop a general adiabatic theory termed the inverse Born-Oppenheimer approximation, in contrast to the conventional Born-Oppenheimer adiabatic theory for molecules in ground or lower excited states, to describe high Rydberg molecules. A thorough theoretical formulation starting from the non-relativistic molecular Hamiltonian and Schrödinger equation is presented with emphasis on the mathematical rigorousness of this theory. Quantitative calculations of the transition rate constants for many radiative and nonradiative processes involved in high Rydberg molecules are shown explicitly. | en_US |
dc.publisher | WILEY-V C H VERLAG GMBH | en_US |
dc.relation.ispartof | JOURNAL OF THE CHINESE CHEMICAL SOCIETY | en_US |
dc.subject | physical chemistry | en_US |
dc.title | Adiabatic theory for high Rydberg molecules | en_US |
dc.type | journal article | en_US |
dc.identifier.doi | 10.1002/jccs.202200394 | - |
dc.identifier.scopus | 2-s2.0-85141413660 | - |
dc.identifier.isi | WOS:000874402900001 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/85141413660 | - |
item.openairetype | journal article | - |
item.fulltext | no fulltext | - |
item.grantfulltext | none | - |
item.openairecristype | http://purl.org/coar/resource_type/c_6501 | - |
item.cerifentitytype | Publications | - |
crisitem.author.dept | Applied Mechanics | - |
crisitem.author.orcid | 0000-0002-5896-6700 | - |
crisitem.author.parentorg | College of Engineering | - |
Appears in Collections: | 應用力學研究所 |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.