https://scholars.lib.ntu.edu.tw/handle/123456789/630635
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Jiang, ZL | en_US |
dc.contributor.author | Wang, J | en_US |
dc.contributor.author | Zhang, HX | en_US |
dc.contributor.author | Liu, WY | en_US |
dc.contributor.author | Wu, ZH | en_US |
dc.contributor.author | Zhao, H | en_US |
dc.contributor.author | Yin, JF | en_US |
dc.contributor.author | Chen, BT | en_US |
dc.contributor.author | Li, YM | en_US |
dc.contributor.author | Yin, PC | en_US |
dc.contributor.author | YI-TSU CHAN | en_US |
dc.contributor.author | Wang, K | en_US |
dc.contributor.author | Chen, MZ | en_US |
dc.contributor.author | Wang, PS | en_US |
dc.date.accessioned | 2023-04-26T02:29:59Z | - |
dc.date.available | 2023-04-26T02:29:59Z | - |
dc.date.issued | 2023 | - |
dc.identifier.issn | 26663864 | - |
dc.identifier.uri | https://scholars.lib.ntu.edu.tw/handle/123456789/630635 | - |
dc.description.abstract | Polyhedra have long appeared throughout art and design for their aesthetic topological features and, more recently, have found versatile roles in supramolecular chemistry and organized materials. Non-regular convex tetrahedra with positive augmentations of a regular tetrahedron, for example an isohedral triakis tetrahedron, have rarely been explored in synthetic chemistry. Herein, we report the synthesis of a giant triakis tetrahedron through multi-component self-assembly from four umbrella-shaped hexa-armed organic terpyridine ligands and six pre-organized cadmium-containing building blocks. Hexafunctionalized tribenzotriquinacene cavitands serve as the scaffold for the formation of the triakis tetrahedron. The convex vertices derived from rhomboid panels form four trigonal-pyramidal cages based on regular tetrahedral faces. Characterization with multiple types of nuclear magnetic resonance spectroscopy, mass spectrometry, atomic resolution microscopy, and X-ray scattering provide crucial structural information on the triakis tetrahedron. The triakis tetrahedron is applied in the photo-driven degradation of a sulfur mustard mimic. The principles developed herein enhance the possible topological diversity of supramolecular coordination polyhedra. | en_US |
dc.language.iso | en | en_US |
dc.publisher | ELSEVIER | en_US |
dc.relation.ispartof | CELL REPORTS PHYSICAL SCIENCE | en_US |
dc.subject | COORDINATION CAGE; DESIGN; POLYHEDRA; ARCHITECTURE; SYMMETRY | en_US |
dc.title | Controlled self-assembly of a giant isohedral triakis tetrahedron | en_US |
dc.type | journal article | en |
dc.identifier.doi | 10.1016/j.xcrp.2023.101293 | - |
dc.identifier.scopus | 2-s2.0-85148353660 | - |
dc.identifier.isi | WOS:000962362000001 | - |
dc.identifier.url | https://api.elsevier.com/content/abstract/scopus_id/85148353660 | - |
dc.relation.journalvolume | 4 | en_US |
dc.relation.journalissue | 3 | en_US |
item.fulltext | no fulltext | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_6501 | - |
item.grantfulltext | none | - |
item.openairetype | journal article | - |
item.languageiso639-1 | en | - |
crisitem.author.dept | Chemistry | - |
crisitem.author.dept | Natural Science and Sustainable Research Promotion and Engagement Center | - |
crisitem.author.orcid | 0000-0001-9658-2188 | - |
crisitem.author.parentorg | College of Science | - |
crisitem.author.parentorg | Others | - |
顯示於: | 化學系 |
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