https://scholars.lib.ntu.edu.tw/handle/123456789/64360
標題: | 普魯士藍修飾電極之電化學鑑定及電致色變反應機制研究 On the Electrochemical Characterization Mechamnism of Prussian Blue Modified Electrodes |
作者: | 何國川 | 關鍵字: | electrochromic;indium hexacyano-ferrate;Pussian blue | 公開日期: | 2001 | 出版社: | 臺北市:國立臺灣大學化學工程學系暨研究所 | 摘要: | The plating solution's stability and the electrodeposition for indium hexacyanoferrate(InHCF), an important analogue of Prussian blue(PB), were greatly ebhanced by adding a large amount of K+ and/or H+. It was found that a 10-mM plating solution added with 1N HCl and 1N KCl could be stored as a fresh one over a week, whereas an unmodified plating solution became useless within couples of minutes. Moreover, the InHCF film grown in an H+-rich environment showed comparatively higher cycle ability, based on the results of electrochemical characterizations. Besides, related enhanced mechanisms were proposed and verified, To sum up, this work has provided a means for better electrodeposition of PD analogues. |
URI: | http://ntur.lib.ntu.edu.tw//handle/246246/9270 | 其他識別: | 892214E002072 | Rights: | 國立臺灣大學化學工程學系暨研究所 |
顯示於: | 化學工程學系 |
檔案 | 描述 | 大小 | 格式 | |
---|---|---|---|---|
892214E002072.pdf | 267.28 kB | Adobe PDF | 檢視/開啟 |
在 IR 系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。