https://scholars.lib.ntu.edu.tw/handle/123456789/66335
標題: | Emulsion-derived lithium manganese oxide powder for positive electrodes in lithium-ion batteries | 作者: | Lu, Chung-Hsin Lin, Shang-Wei |
公開日期: | 2001 | 期: | 93 | 起(迄)頁: | 14-19 | 來源出版物: | Journal of Power Sources | 摘要: | Lithium manganese oxide (LiMn2O4) used as a positive-electrode material in lithium-ion batteries is prepared by a new water-in-oil emulsion process. An aqueous solution containing lithium and manganese cations is emulsified in kerosene by adding sorbitan monooleate as the surfactant. When the precursor solution is agitated by a magnetic mixer, impure products are obtained. LiMn2O4 is formed along with residual Mn2O3 at elevated temperatures because of insufficient dispersion and mixing of the reactive cations. When a homogenizer with a greater agitation speed is used, however, a well-mixed precursor solution is prepared, and pure LiMn2O4 with a Fd 3 m structure is synthesized after calcination at 800 °C for 1 h. LiMn2O4 powder prepared by the homogenizer has higher crystallinity, smaller particle size, and narrower size distribution than that prepared by the magnetic stirrer. Compared with powder prepared by the solid-state method, the LiMn2O4 powder exhibits smaller particle size and less agglomeration. Moreover, the emulsion process significantly shortens the heating time required. The prepared LiMn2O4 powder has a high discharge capacity (120.4 mA h g-1) on the first cycle and good cycleability. |
URI: | http://ntur.lib.ntu.edu.tw//handle/246246/92072 | DOI: | 10.1016/S0378-7753(00)00515-2 | SDG/關鍵字: | Calcination; Crystalline materials; Electrochemical electrodes; Emulsions; Lithium; Particle size analysis; Positive ions; Powders; Solutions; Synthesis (chemical); Lithium ion batteries; Electric batteries |
顯示於: | 化學工程學系 |
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