A general synthesis of vinylic silyl hydrides using nickel catalysis. Applications to the syntheses of silylene-tethered conjugated polymers

Chen, R.-M.R.-M.ChenTIEN-YAU LUH2018-09-102018-09-101998http://www.scopus.com/inward/record.url?eid=2-s2.0-0032510208&partnerID=MN8TOARShttp://scholars.lib.ntu.edu.tw/handle/123456789/338717Treatment of benzylic or allylic dithioacetals with Me2((i)PrO)SiCH2MgCl in the presence of NiCl2(PPh3)2 catalyst yielded the corresponding i-propoxy(vinyl)silanes which are reduced with LiAlH4 to afford vinylic silyl hydrides. These hydrides serve as the precursors for the syntheses of silylene-tethered σ,π-conjugated copolymers.application/pdfapplication/pdf[SDGs]SDG6A general synthesis of vinylic silyl hydrides using nickel catalysis. Applications to the syntheses of silylene-tethered conjugated polymersjournal article10.1016/S0040-4020(97)10218-62-s2.0-0032510208WOS:000071628500017