呂宗昕2006-07-252018-06-282006-07-252018-06-282004-06-01http://ntur.lib.ntu.edu.tw//handle/246246/9391本研究成功利用微乳膠製程合成 高性能之奈米級銪離子添加之釔鋁柘 榴石Y3Al5O12 (YAG)螢光粉,藉由控微 乳膠系統中適當之油相與水相比例, 可獲得穩定且澄清之微乳膠系統,單 相YAG: Eu 3+ 可於1100 o C 四小時之空 氣氣氛下煆燒合成,單相溫度與固相 法相比低了將近600 o C 。隨煆燒溫度之 升高,合成之螢光粉均為奈米級且分 散良好之圓球狀粉體。利用真空紫外 光激發所得之放射光譜,進一步證實 了微乳膠法合成之YAG: E u 3+ 為一極 具發展潛力之電漿顯示器用螢光材料。The microemulsion process was successfully developed for synthesizing europium-ion doped yttrium aluminum garnet (YAG: Eu 3+ ) nanoparticles. A thermodynamically stable and transparent microemulsion system was obtained by dissolving suitable water-to-oil ratio. YAG: Eu 3+ with a single phase was obtained after calcination at 1100 o C for 4 h in air. The formation of single-phase YAG via the microemulsion process is approximately 600℃lower than that via the solid-state reaction. As increasing in the calcination temperature, the phosphors still maintained in the nano-sized range with spherical and dispersed morphology. The emission spectra under the excitation of VUV light confirm the application of YAG: Eu 3+ phosphors for plasma display panels.application/pdf202011 bytesapplication/pdfzh-TW國立臺灣大學化學工程學系暨研究所微乳膠法釔鋁柘榴石奈米粉體螢光材料螢光釔鋁石榴石型材料之溶液法製備及結構與特性分析(1/3)Solution Synthesis, Structural Analysis, and Characterization of Yttrium Aluminum Garnet Phosphorsreporthttp://ntur.lib.ntu.edu.tw/bitstream/246246/9391/1/922214E002036.pdf