林曉武2006-07-252018-06-282006-07-252018-06-282002http://ntur.lib.ntu.edu.tw//handle/246246/14802本研究在探討高有機碳沉機環境中硫酸鹽還原與硫化礦物形成與控制 機制。研究分析項目包括有機與無機碳含量,氯與硫酸鹽含量, 硫化礦物(AVS, FeS2),硫酸鹽還原速率等。研究結果顯示在高有機碳沉降之無氧海洋沉積環境 其C/S ratio 卻具有陸源但缺硫之沉積環境, 造成此種特殊現象之主要原因為 沉積環境缺鐵所產生。 大鵬灣上層海水之鹽度多為近正常海水之半鹹水,故顯示出大鵬灣沈積 物應屬於一般海洋沈積物而非淡水沈積環境,即硫酸鹽濃度不虞匱乏,而有機碳 之含量亦非常之高,但此研究區域有出現部分淡水環境特性(即C/S 比值較高), 原因可能是黃鐵Pyrite-S 含量過低所致,而黃鐵礦Pyrite-S 含量過低的原因為, 即可能主要是受到活性鐵含量低所限制。故而從此屬於半鹹水之沈積環境中,可 發現同時具有淡水與正常海水沈積環境之特徵,而其淡水沈積環境特徵之突出, 更顯示在古沈積環境學上,一般常常使用C/S 比值來定義正常海洋沈積環境或淡 水沈積環境是有明顯的缺失,如果沈積環境內活性鐵缺乏,是可能將正常海洋環 境中之C/S 比值轉變成具有淡水沈積環境C/S 比值之特徵。故在古沈積環境之界 定上就更需小心是否有類似之沈積環境所產生之誤導現象。This research studied sulfate reduction and pyrite formation in the iron limited brackish sedimentary environment. Sulfate reduction rate, sulfate, chloride, organic and inorganic carbon concentrations were analyzed for sediments collected from Da-Pang Bay. The result showed that Da-Pang Bay sediment is characterized by high organic carbon, AVS and pyrite concentrations. Higher concentrations of AVS and organic carbon were mostly observed in sediments away from the bay opening whereas higher pyrite concentrations were observed in sediments mostly around the higher concentrations of AVS. High concentrations of chloride indicate the environment is mostly marine and abundant sulfate indicate that sulfate is unlikely a limiting factor for the pyrite formation. The C/S ratio, however, resembles that of the freshwater depositional environment. The discrepancy was primarily a result of iron limitation.application/pdf109699 bytesapplication/pdfzh-TW國立臺灣大學海洋研究所硫酸鹽還原黃鐵硫化礦物無氧沉積物sulfate reductionpyritesulfideanoxic sediments[SDGs]SDG14季節性硫酸鹽還原與硫化礦物物種之變化(Ⅱ)reporthttp://ntur.lib.ntu.edu.tw/bitstream/246246/14802/1/902611M002008.pdf