Tan, Kok-HouKok-HouTanYANG-HSIN SHIHWEN-LING CHEN2024-04-152024-04-152024-0500456535https://scholars.lib.ntu.edu.tw/handle/123456789/641919https://doi.org/10.1016/j.chemosphere.2024.141710Natural organic matter is a mixture of microbial decomposition products widely found in surface and groundwater. These organic materials have great potential as carbon-based precursors for chemical synthesis. This work demonstrated the development of a green photocatalyst via a facile adsorption process that combined colloidal titanium dioxide (TiO2) with humic acid. The resulting photocatalyst was visible light active and able to completely degrade 5 mg/L of BPA within 6 h under the irradiation of energy-efficient LED white light. The first-order kinetic rate constant of the reaction was determined to be 1.7 × 10-2 min-1. The enhanced photocatalytic activity was attributed to the decreased band gap energy and effective charge separation that limits the photogenerated electron-hole recombination. The outcome of this research opened an opportunity for the development of sustainable functional materials using natural organic matter.enPhotocatalysisTitanium dioxideNatural organic mattersVisible lightOrganic pollutantsFacile preparation of environmental benign LED white light active humic acid nanolayer coated titanium dioxide photocatalyst for bisphenol A degradationjournal article10.1016/j.chemosphere.2024.141710384939982-s2.0-85188784321https://api.elsevier.com/content/abstract/scopus_id/85188784321