2010-08-012024-05-18https://scholars.lib.ntu.edu.tw/handle/123456789/700418摘要：本研究為三年期之計畫。我們將以超音波技術結合電化學與濕式化學方法製備規則垂直成長於基材的陣列式一維奈米結構金屬氧化物材料，包括二氧化鈦奈米管/奈米棒陣列與氧化鋅奈米線陣列。為有效利用一維奈米結構材料的異向性質與獲得預期之效能，我們先系統性地探討製備&#63851;&#63849;對一維奈米結構材料的幾何尺寸、結晶程度及表面型貌的影響，同時控制一維奈米結構材料在適當基材與位置定向規則成長，以獲得預期的效能。接著，為增加反應面積與提高表面反應活性，我們將利用電泳沉積法以及新穎之一步驟模版輔助製備法，填充金屬氧化物奈米顆粒於一維奈米結構材料內與間隔空間；同時，採用簡易操作的光化學與濕式化學方法塗佈金屬或金屬氧化物層修飾所製得材料的表面特性。我們預期本研究所研製的新穎功能性一維奈米結構材料陣列可作為光觸媒及光電極材料，整合應用於光催化與光電催化系統，高效率地轉化新興污染物(如藥品與個人保健用品中的乙醯氨酚與異布洛芬)為環境友善之無毒最終產物。本研究預計開發創新的方法獲得高效率、陣列式一維奈米結構光觸媒及電極材料並用於降低新興污染物對人體健康及生態環境的威脅。<br> Abstract: In this 3-year project, high-ordered vertical-aligned 1-D nanostructured metal-oxide arrays, such as TiO2 nanotube/nanorod arrays and ZnO nanowire arrays, will be fabricated using the combination of sonoelectrochemical anodization method and wet-chemical route. To properly utilize the anisotropic properties of 1-D nanostructured metal-oxide arrays in applications with high performance, the influences of the fabrication parameters on the properties of the prepared materials, such as geometries, crystallinity, and shapes, will be systematically investigated. The growth of the 1-D nanostructured metal-oxide arrays will be controlled onto the selected substrates and positions, followed by the filling of the 1-D nanostructures with the metal-oxide nanoparticles using electrophoresis deposition and novel one-step template-assisted method. The functionalization of the metal nanoparticles and metal-oxide layers on the above prepared materials will be carried out by the photochemical method and the wet-chemical route. The prepared novel 1-D nanostructured metal-oxide arrays will act as highly efficient photocatalysts and photoanode in the applications of photocatalysis and photoelectrocatalysis to completely transform the emerging contaminats (e.g., pharmaceuticals and personal care products, PPCPs) into environmentally benign end-products. This project will allow us to better understand the related mechanisms on the growth of 1-D nanostructures and the toxicity of PPCPs in order to develop more environmentally friendly PPCPs treatment techniques with nanotechnology.一維奈米結構奈米顆粒電化學電泳沉積法光催化光電催化乙醯氨酚異布洛芬one-dimensional nanostructured materialsnanoparticleselectrochemicalelectrophoresis depositionphotocatalyticphotoelectrocatalyticPPCPs