指導教授：邱勝賢臺灣大學：化學研究所吳宇耕Wu, Yu-GengYu-GengWu2014-11-252018-07-102014-11-252018-07-102014http://ntur.lib.ntu.edu.tw//handle/246246/261264我們合成了一個可與C60形成室溫下可被分離之活門囚籠錯合物(hemicarceplex)之分子牢籠。利用此一分子，我們可以自市售之富勒烯萃取物(fullerene extract)中直接分離純化出純度≥98%之C60，毋須經過液相層析或再結晶的程序。A cyclotriveratrylene-based molecular cage that favors the formation of a room temperature isolable C60-incarcerated hemicarceplex had been synthesized. Significant differences in the association and dissociation kinetics of the molecular cage and fullerenes allowed the isolation of C60 in high purity (≥98.0%) from a commercial fullerene extract without the need for recrystallization or HPLC.目錄.........iii 圖目錄.......iv 表目錄.......v 流程目錄.... vi 1.1 簡介.... ............................2 1.1.1 前言...... ........................2 1.1.2 環三聚藜烴 ....................... 3 1.1.3 富勒烯萃取物.......................4 1.1.4 分離純化富勒烯 ................... 6 1.1.5 分子容器與客體分子的關係.......... 9 1.2 研究動機............................ 10 1.3 分子設計與合成...................... 10 1.4 分子鍵結行為與穩定性................ 13 1.5 分離純化市售富勒烯萃取物中的C60..... 17 1.6 結論................................ 20 實驗部分 ............................... 21 參考文獻 ............................... 28 附錄.................................... 303465975 bytesapplication/pdf論文使用權限：不同意授權囚籠錯合物thesishttp://ntur.lib.ntu.edu.tw/bitstream/246246/261264/1/ntu-103-R01223164-1.pdf