Yang C.-HLiu Y.-HPeng S.-MSHIUH-TZUNG LIU2022-12-142022-12-14202224688231https://www.scopus.com/inward/record.uri?eid=2-s2.0-85126514310&doi=10.1016%2fj.mcat.2022.112232&partnerID=40&md5=7859e6947f6c28de55e8891543592546https://scholars.lib.ntu.edu.tw/handle/123456789/626327Reaction of iridium complex [Ir(N,C-dFppy)2(L)Cl] (Ir-1) [L = 5-phenyl-2,8-di-2-pyridinyl-anthyridine] with (CH3CN)PdCl2 to yield a hetero-binuclear complex Ir-Pd via ortho-metallation. Complexes were characterized by spectroscopic and crystallographic methods. Complex Ir-Pd shows an excellent catalytic activity for both Suzuki-Miyaura and Sonogashira cross coupling reactions under blue LED irradiation at ambient temperature. This catalytic system is operated via light energy harvested by the Ir center, which is able to cooperate with Pd center for the coupling reactions to take place. Effects on these coupling reactions catalyzed by Ir-Pd under photochemical conditions were studied. © 2022Iridium; Palladium; Photo-catalysis; Sonogashira coupling; Suzuki-Miyaura couplingBinary alloys; Catalysis; Iridium compounds; Palladium alloys; Palladium compounds; Photochemical reactions; Binuclear complexes; Coupling reaction; Iridium complex; Orthometallation; Photo-catalysis; Reaction catalyzed; Sonogashira coupling; Sonogashira coupling reactions; Suzuki-Miyaura coupling; Suzuki-Miyaura coupling reaction; Catalyst activityjournal article10.1016/j.mcat.2022.1122322-s2.0-85126514310