Chang, Ke-WeiKe-WeiChangLai, Ting-YiTing-YiLaiChin, To-JenTo-JenChinAnitha, MandalaMandalaAnithaLiu, Yi-HungYi-HungLiuIshiwari, FumitakaFumitakaIshiwariSaeki, AkinoriAkinoriSaekiJEFFREY M. FARRELL2026-01-122026-01-122025https://scholars.lib.ntu.edu.tw/handle/123456789/735238Despite modest steric demands and a labile substituent, B-brominated boron-doped polycyclic aromatic hydrocarbons (PAHs) can participate in frustrated Lewis pairs. This is exploited for B-alkynylation and functionalization of boron-doped PAHs, enabling deep LUMO levels, solid-state 1D π-stackings, and long-wavelength emissions extending into the near-infrared.enjournal article10.1039/d5cc05480j