2015-05-012024-05-16https://scholars.lib.ntu.edu.tw/handle/123456789/668318摘要：本子計畫將針對以石墨烯氧化物及其還原態為基礎材料(以下簡稱石墨烯)，發展非貴金屬-石墨烯之複合結構，探討其光電與觸媒特性暨光催化二氧化碳產生低碳氫燃料之應用。除了以非貴金屬強化光催化，我們也將結合二硫化鉬等二維半導體或有機光敏分子與石墨烯來形成複合結構，研究異質結構間的能量與電荷轉移現象，及其光催化特性。對這多元材料系統，我們打算建立基礎理論/計算分析方法以模擬可能表面結構，並探討光催化反應機制。<br> Abstract: This subproject will focus on the fundamentals of photon management and carrier transfer in hybrid low-dimensional carbon nanocomposites-based light harvesting systems for solar-fuel applications, with an emphasis on carbon dioxide conversion. The specific aim is to develop graphene oxides (GOs) and reduced GOs and their hybrids with tunable bandgap and band alignment with respect to the energy levels of CO2 reduction. The ultimate goal is to establish GO-based photocatalysts for CO2 reduction to hydrocarbons under visible light. A series of GO-based hybrids with metals, non-graphene two-dimensional materials such as metal sulfides, and organics sensitizers will be investigated. Theoretical support for the design of materials and the understanding of their surface behaviors with the resultant photocatalytic activity will be conducted.石墨烯有機光敏分子二維半導體光催化二氧化碳還原低碳氫燃料Graphene oxidestwo-dimensional materialsorganic sensitizersphotocatalysisCO2 reduction