2020-03-012024-05-14https://scholars.lib.ntu.edu.tw/handle/123456789/656282In this proposal, we aim to design the nanocluster carbon materials composite to enhance our recent developed Cu‒Cu(I) ensembles (CuOx) for CO2 electrochemical reduction reaction (eCO2RR), as conceptually shown in Figure 1. We approach such ultimate goal through the following three original and complementary expertise – (1) first-principle simulations combining machine learning analysis, (2) electrochemical growth and in-situ spectroscopic characterization for realistic visualization in catalytic activity, (3) mass-production in functionalized carbon material electrode for sub-nanometer catalyst growth. This integrated catalytic system targets to improve electrochemical energy-efficiency and prolong the redox stability for the future industrial scale application.臨場碳催化in situcarboncatalysis