Chen H.-PKu R.-ZSHIUH-TZUNG LIU2022-12-142022-12-14200100094536https://www.scopus.com/inward/record.uri?eid=2-s2.0-18944400006&doi=10.1002%2fjccs.200100003&partnerID=40&md5=f584ca105cac0560e5b76ad29666af99https://scholars.lib.ntu.edu.tw/handle/123456789/626247Diamino-carbene ligand transfer between various metal ions is studied, particularly with Pd(II) to Rh(I), Rh(I) to Au(I). Reactions of various carbene complexes with AgPF6 result in the cleavage of the M=C bond to give the protonated carbene species, imidazolidin-2-ylidinium salt, indicating the presence of free carbene ligand in the reaction medium. When the carbene transfer process was carried out in tetrahydrofuran, the polymerization of tetrahydrofuran occurred.Carbene transfer; Diaminocarbenes; Transition metal ionsjournal article10.1002/jccs.2001000032-s2.0-18944400006