Ke, YuanzhenYuanzhenKeWang, Hsian WenHsian WenWangLiu, ZhichangZhichangLiuTIEN-YAU LUH2023-09-042023-09-042023-02-2300397881https://scholars.lib.ntu.edu.tw/handle/123456789/635012Oxygen ligands have been shown to play a critical role in the formation and organization of metalloporphyrin assemblies and natural chlorosomes. In this work, mutually complementary head-totail dimers of zinc(II) porphyrins were synthesized through the coordination of zinc with the imide group and 7-oxanorbornene oxygen ligands. UV/Vis absorption and emission, 1H NMR as well as FT-IR analyses were used to determine the structure. The dimerization association constant K has been determined to be 5.6 M-1 and 29 M-1, respectively, by the dilution experiment.enaggregation | coordination | dimerization | metalloporphyrins | oxygen ligands | self-assemble[SDGs]SDG3journal article10.1055/a-2079-38652-s2.0-85166965852https://api.elsevier.com/content/abstract/scopus_id/85166965852