謝國煌臺灣大學：高分子科學與工程學研究所李其欣Li, Chi-HsinChi-HsinLi2007-11-292018-06-292007-11-292018-06-292004http://ntur.lib.ntu.edu.tw//handle/246246/62883本研究主要合成含羧酸基之紫外光可硬化樹脂及導電高分子聚苯胺，利用特殊官能基間的自組裝性質以及微影技術，製備全高分子組成之透明導電線路薄膜，並開發最佳化製程程序。 以丙烯酸為單體，與PPG700、PPG400寡聚物合成之Urethane Acrylate混摻，成它X成具有活性官能基-COOH之紫外光可硬化樹脂。以紫外光透過光罩曝光進行交聯反應，顯影後獲得5~100μm線寬之圖案。藉由官能基間特殊引力作用反應，將苯胺單體自組裝至活性官能基表面後，再以原位聚合反應聚合得聚苯胺。 利用FT-IR鑑定樹脂組成、GPC分析樹脂分子量，以OM及AFM觀察Pattern外觀型態，使用UV-Vis吸收光譜與ESCA鑑定聚苯胺自組裝結果，熱性質方面使用TGA與DSC分析，最後以四點探針法量測導電性，UV-Vis穿透光譜測量透明度。 本實驗結果可獲得導電度10 S/cm、透明度約70%之透明導電薄膜，之後在熱性質及微影圖案的細緻型態表現上再做改進，將可達到實際的產業應用性。In this study, we synthesized UV-curable acrylates with carboxylic acid groups as substrate for self-assembly processing in producing conductive polyaniline. The conductive pattern by self assembly techniques was developed. Develop the optimum produce process. Acrylic acid was used as monomer to blend with urethane acrylates in order to synthesize the UV-curable acrylates with carboxylic acid. The pattern with 5~100μm line-width was prepared by lithography technique. The aniline monomer was self-assembled to the carboxylic acid groups on the pattern by the molecular attraction to form complex. The “in-situ polymerization” to polymerize PANi was conducted further in the aqueous solution. We used FT-IR to identify the structure of resins. And used GPC to analyze their molecular weight. The morphology of patterns were observed by OM and AFM. UV-Vis spectroscopy & ESCA were employed to identify the self-assembly results of PANi. In thermal properties, TGA and DSC were used to analyze our samples. Finally, we use the four-probes method to measure the sheet resistivity and use the UV-Vis spectroscopy to analyze their transparency. The transparent conducting membrane with conductivity about 10 S/cm and mean transparency over 70% was obtained. The performance of the transparent conductive membrane can be improved further for the commercial applications.摘要………………………………………………………………………...I Abstract…………………………………………………………………….II 目錄……………………………………………………………………….III 表索引………………………………………………………………...…...V 圖索引…………………………………………………………………...VII 第一章 緒論…………………………………………………………….....1 1-1 可撓式透明導電膜………………………………………….1 1-2 本文研究目的.…………………………………………........2 第二章 文獻回顧………………………………………………………….4 2-1 透明導電膜................................................................................4 2-2 聚胺酯與紫外光可硬化樹脂…………………………………9 2-3 導電高分子—聚苯胺……………………………………......12 2-4 微影技術簡介……………………………………………......20 2-5 自組裝原理與應用……………..………………………….22 第三章 實驗方法………………………………………………………...26 3-1 實驗藥品…………………………………………………......26 3-2 使用儀器…………………………………………………......30 3-3 實驗流程…………………………………………………......33 3-4 實驗步驟…………………………….……………………….38 3-5 性質測試…………………………………………………......42 第四章 結果與討論………………………………………………….......46 4-1含羧酸基之紫外光可硬化樹脂製備與特性分析……….......46 4-1-1 化學結構分析………………………………….……...46 4-1-2 熱性質分析………………………………….………...48 4-2 微影製程分析………………………………………..………53 4-3導電膜線路圖案分析………………………………..……….56 4-3-1線路圖像轉移結果分析……………………..…………57 4-3-2 自組裝性質分析…………………………….………...59 4-3-3 熱性質分析………………………………….………...63 4-3-4 透明度分析………………………………….………...68 4-3-5 導電性質分析………………………………….……...70 第五章 結論……………………………………………..……………….75 第六章 參考文獻……………………………………..………………….775384227 bytesapplication/pdfen-US丙烯酸微影紫外光可硬化樹脂原位聚合反應聚苯胺自組裝UV-Curable ResinIn-situ polymerizationself-assemblePolyanilineLithographyAAthesishttp://ntur.lib.ntu.edu.tw/bitstream/246246/62883/1/ntu-93-R91549007-1.pdf