Wang Y.Zhang Z.Zhang L.Luo Z.Shen J.Lin H.Long J.Wu J.C.S.Fu X.Wang X.Li C.2019-05-032019-05-03201800027863https://scholars.lib.ntu.edu.tw/handle/123456789/406424A marigold-like SiC@MoS 2 nanoflower with a unique Z-scheme structure efficiently achieves the overall conversion of gas phase CO 2 with H 2 O (CO 2 (g) + 2H 2 O (g) = CH 4 + 2O 2 ) without any sacrificial reagents under visible light (£f ? 420 nm) irradiation. The CH 4 and O 2 evolution are 323 and 621 £gL¡Pg -1 ¡Ph -1 , and stable throughout 5 cycle reactions of total 40 h. This work demonstrates a breakthrough in artificial photosynthesis with the Z-scheme 1D heterojunction constructed by combining 2D semiconductor and 3D semiconductor based on the transfer balance of photogenerated electron and hole. ? 2018 American Chemical Society.journal article10.1021/jacs.8b093442-s2.0-85056120832https://www.scopus.com/inward/record.uri?eid=2-s2.0-85056120832&doi=10.1021%2fjacs.8b09344&partnerID=40&md5=6d9265c13ae5b56d3e819c0f16d01fd5