Kao, Y.-W.Y.-W.KaoLee, W.-H.W.-H.LeeJeng, R.-J.R.-J.JengHuang, C.-F.C.-F.HuangWu, J.Y.J.Y.WuLee, R.-H.R.-H.LeeRU-JONG JENG2018-09-102018-09-102015http://www.scopus.com/inward/record.url?eid=2-s2.0-84940461580&partnerID=MN8TOARShttp://scholars.lib.ntu.edu.tw/handle/123456789/390573In this study we prepared three star-shaped, triphenylamine-cored conjugated molecules, possessing thienylenevinylene units as conjugated π bridges and thienyl, 2-ethylhexyl cyanoacetate, and 1,3-diethyl-2-thiobarbituric acid moieties, respectively, as peripheral groups - for use as donor materials in small molecule/fullerene bulk heterojunction-type organic photovoltaic cells (OPVs). The peripheral groups affected the UV-Vis absorption behavior and electrochemical properties of star-shaped molecules, and photovoltaic performance of the star-shaped molecules based OPVs. The wavelength of maximum absorption for star-shaped molecule with 1,3-diethyl-2-thiobarbituric acid moiety was red-shifted relative to those of molecules with thienyl and 2-ethylhexyl cyanoacetate groups, while molecule with thienyl moiety exhibited the largest hole mobility. The photovoltaic properties of cells incorporating molecule with thienyl group and a fullerene derivative were better than those containing corresponding molecule with 2-ethylhexyl cyanoacetate/fullerene or molecule with 1,3-diethyl-2-thiobarbituric acid/fullerene blends. An OPV featuring molecule with thienyl group/fullerene derivative (1:3, w/w) as the active layer exhibited a power conversion efficiency of 1.43%, a short-circuit current density of 5.23 mA/cm2, an open-circuit voltage of 0.73 V, and a fill factor of 0.37. © 2015 Elsevier B.V. All rights reserved.Bulk heterojunction cell; Photovoltaic performance; Star-shaped molecules; Triphenylamine[SDGs]SDG7Heterojunctions; Hole mobility; Open circuit voltage; Organic solar cells; Photoelectrochemical cells; Photovoltaic cells; Photovoltaic effects; Red Shift; Solar power generation; Stars; Bulk heterojunction; Conjugated molecules; Organic photovoltaic cell (OPVs); Photovoltaic performance; Photovoltaic property; Power conversion efficiencies; Star-shaped molecules; Triphenyl amines; Moleculesjournal article10.1016/j.matchemphys.2015.07.024