HSIN-JAY WUChen, Sinn-WenSinn-WenChenIkeda, TeruyukiTeruyukiIkedaJeffrey Snyder, G.G.Jeffrey Snyder2024-09-182024-09-182012https://www.scopus.com/record/display.uri?eid=2-s2.0-84866728965&origin=resultslisthttps://scholars.lib.ntu.edu.tw/handle/123456789/721193Pb-alloyed AgSbTe 2 (Pb xAg 20Sb 30-xTe 50 (x = 3, 4, 5 and 6)) composites were synthesized using a modified Bridgman method with a graphite mold to form plate-like samples. The Bridgman-grown specimens were dense, with few solidification cavities, and were sufficiently mechanically robust for a variety of electronic/thermal transport measurements. Inhomogeneity was found on the grain boundary, and was embedded with the nanoprecipitates of δ-Sb 2Te with a feature size of 100 nm of the 5 at.% Pb and 6 at.% Pb specimens. A combined effect of alloying, inhomogeneity and nanoprecipitates leads to a low thermal conductivity of 0.3-0.4 W m -1 K -1, which approaches the theoretical minimum thermal conductivity of the amorphous material (κ min ∼ 0.36 W m -1 K -1). A peak of the zT value, ranging from 0.7 to 0.8, is achieved at 425 K. Further annealing at 673 K increases the grain size and causes a reduction in the value of the zT peak to 0.4. © 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.AgSbTe 2BridgmanNanoprecipitateThermal conductivityThermoelectricjournal article10.1016/j.actamat.2012.07.0572-s2.0-84866728965