邱勝賢Chiu, Sheng-Hsien臺灣大學:化學研究所翁梓桓Wong, Tzu-HuanTzu-HuanWong2010-06-302018-07-102010-06-302018-07-102009U0001-2007200912223000http://ntur.lib.ntu.edu.tw//handle/246246/187517運用實驗室先前發展出來之ＣＴＶ為基礎的分子容器合成策略，合成以dibenzo-30-crown-10為架構之ＣＴＶ分子容器。將分子容器與適當之客體分子做錯合的研究，從NMR氫譜上可以看到明顯之化學位移改變，可推測我們的分子容器對此客體分子有錯合之作用。We have synthesized the cyclotirveratrylene molecular container based on dibenzo-30-crown-10 using the method we developed before. We studied the complex character between the molecular container and appropriate guest molecule. It showed that the chemical shift of the 1H-NMR spectra moved obviously. We supposed there were some interaction between our molecular container and the guest molecule.謝誌 ..............................................................I文摘要 .........................................................III文摘要 .........................................................IV錄 ............................................................. V表 ............................................................VII程 ............................................................. X格 ............................................................ XI、 導論 ...................................................... 1.1前言 ......................................................... 1.2超分子化學的發展與冠醚的起源 ................................. 3.3超分子系統 ................................................... 7.3.1 主客化學 (Host -guest chemistry) ........................... 7.3.2 杯芳烴 (Calixarene） ....................................... 8.3.3 分子監獄 (Carcerand ) .................................... 9.3.4 準車輪烷 (Psudortaxane) ................................. 10.4 環三聚藜烴 ( Cyclotriveratrylene ) ............................... 15.5 環三聚藜烴衍生物之應用 ....................................... 17、 結果與討論 ................................................ 25.1研究動機 ......................................................25.2目標分子的合成 .................................................27.3錯合測試 ......................................................29、 結論 ...................................................... 39、 實驗部分 .................................................. 40、 參考文獻 .................................................. 47、 附錄 ...................................................... 533817641 bytesapplication/pdfen-US超分子化學環三聚藜烴分子容器Supramolecular ChemistrycyclotirveratryleneMolecular Container以CTV為基礎之籠狀分子與銨鹽的錯合研究The Complexation of a CTV-Based Molecular Container to Tetra-alkyl Ammonium Saltsthesishttp://ntur.lib.ntu.edu.tw/bitstream/246246/187517/1/ntu-98-R96223141-1.pdf