Pai M.-HHu C.-CGUEY-SHENG LIOU2022-03-222022-03-22202110221336https://www.scopus.com/inward/record.uri?eid=2-s2.0-85116883634&doi=10.1002%2fmarc.202100492&partnerID=40&md5=5340a9c177178b3b33bb6b1ea64c265bhttps://scholars.lib.ntu.edu.tw/handle/123456789/600321The formation of Tr?ger's Base (TB) configuration is a useful approach to synthesize polymers of intrinsic microporosity (PIM). Herein, the V-shaped TB scaffold is incorporated to prepare electrochromic (EC) polyamide with electroactive triphenylamine (TPA) moiety. The presence of intrinsic microporosity derived from inefficient packing of TB scaffolds can facilitate the counterions diffusion between electroactive species and electrolytes. Consequently, the resulting TB-based polyamide exhibits enhanced EC behaviors, such as a lower driving potential, reduced the difference of redox potentials ΔE, and shorter switching response time compared to the corresponding EC counterpart polyamide. ? 2021 Wiley-VCH GmbHelectrochromicintrinsic microporosityresponse capabilityTr?ger's baseMicroporosityPolyamidesRedox reactionsScaffoldsElectro activesElectrochromic switchingElectrochromicsIntrinsic microporosityMicroporousPolyamide filmsPolymers of intrinsic microporositiesResponse capabilitySwitching propertiesTroger baseElectrochromismamineelectrolytenylonpolymerAminesElectrolytesNylonsPolymers[SDGs]SDG7journal article10.1002/marc.202100492345538022-s2.0-85116883634