指導教授：林英智臺灣大學：化學研究所蘇娣Mendiratta, ShrutiShrutiMendiratta2014-11-252018-07-102014-11-252018-07-102014http://ntur.lib.ntu.edu.tw//handle/246246/261275本論文研究以手性含氮有機配子與過渡金屬鹽反應，設計合成九個新型手性金屬有機配位化合物(Metal-Organic Frameworks, MOFs)。化合物{[Zn2(L-trp)2(bpe)2(H2O)2]‧2H2O‧2NO3}n (1)、 {[Co(L-trp)(bpe)(H2O)]‧H2O‧NO3}n (2) 、 {[Co(L-trp)(bpa)(H2O)]‧H2O‧NO3}n (3) 為二維手性結構，具有（4,4）矩形孔洞狀拓撲。化合物[Zn2(Hbbim)2(bbim)]n (4)為二維蜂巢(honeycomb)結構，具有(6,3)拓樸網狀特徵。化合物{{[Mn(bbim)(H2bbim)]‧CH3OH}{[Mn(bbim)(H2bbim)]‧H2O}}n (5) 是一維zig-zag 鍊狀結構，化合物[Mg(phen)(bdc)]n (6) 是不含客分子且是罕見cds-型三維有機金屬配位聚合物。化合物{[Ni2(bbim)(H2bbim)4]‧2CH3COO‧CH3CN}2 (7)、化合物{[Ni(H2bbim)3]‧2Cl‧2H2O} (8) 及化合物D/L-{[Cr(Hbbim)3]‧3H2O} (9)藉由客分子間氫鍵形成超分子。另人驚奇的是，外消旋化合物D/L-{[Cr(Hbbim)3]‧3H2O} (9)是非常獨特的結構，含有一組4員環螺旋槳狀的水團簇呈外消旋而聚在一起，其中兩兩互為鏡像的螺旋物，彼此互穿而形成三維結構，具有103網狀具srs拓樸特徵。到目前為止，內類似化合物9含有相同手性之鏡像異構物，進行掌性分子辨識和自組裝，在超分子的領域尚未被報導過。 本論文研究詳細探討新合成化合物的介電性質，發現化合物1及4為低介電物質。化合物1的介電常數值 (κ = 2.53，1 MHz)，相近似於沸石咪唑骨架結構物(ZIFs)。其獨特陰離子能夠調控物質的介電數值，發現當陰離子的極化增加時，其介電常數會隨之增大。此外，化合物1為良好的發光材料(為546 nm的綠光)和非線性光學材料，產生二次倍頻 (second harmonic generation, SHG)的效能約SiO2的兩倍。令人值得注意的是，化合物4的介電常數低於已報導過的ZIFs結構物，由於它是一個層狀結構物，且各層間並不存在水分子，它是一個非常有用的低介電及高度熱穩定的物質。調變頻率進行介電性的研究，顯示化合物7和8的介電常數(κ)和介電損耗有明顯差異，可能由於結構和所含的溶劑分子的類型不同所造成。本論文在物質結構及相關基礎的研究，發現客分子之調控，對於高介電係數或低介電係數材料之設計，可作為重要之參考。A series of chiral metal-organic frameworks (MOFs) and supramolecular compounds were synthesized by reacting nitrogen containing ligands with transition metal salts and their dielectric behavior was investigated. The structures of these compounds range from one dimensional zig-zag chains to three dimensional structures. Compounds 1~4 were found to be chiral, with two dimensional structures. Compounds {[Zn2(L-trp)2(bpe)2(H2O)2]‧2H2O‧2NO3}n (1), {[Co(L-trp)(bpe)(H2O)]‧H2O‧NO3}n (2) and {[Co(L-trp)(bpa)(H2O)]‧H2O‧NO3}n (3) displayed a common framework with a rectangle- like (4,4) topology, whereas compound [Zn2(Hbbim)2(bbim)]n (4) has a honeycomb structure with a (6,3) connected net. Compound {{[Mn(bbim)(H2bbim)]‧CH3OH}{[Mn(bbim)(H2bbim)]‧ H2O}}n (5) was found to be a one dimensional coordination polymer with a zig-zag chain structure. Compound [Mg(phen)(bdc)]n (6) was a guest free 3D compound and serves as a rare example of a cds-type framework. Compounds {[Ni2(bbim)(H2bbim)4]‧2CH3COO‧CH3CN}2 (7), {[Ni(H2bbim)3]‧2Cl‧2H2O} (8) and D/L-{[Cr(Hbbim)3]‧3H2O} (9), were supramolecular compounds forming extended structures via extensive hydrogen-bonding with the guest molecules. The racemic compound D/L-{[Cr(Hbbim)3]‧3H2O} (9) had a very unique molecular-propeller structure, in which the D/L-molecular propellers were glued together by rare water tetrahedrons. Astonishingly, the packing arrays formed by the enantiomeric propellers of one chirality were interpenetrated with those of the opposite chirality to form specific 3D supramolecular arrays with 103 nets and srs topology. This chiral discrimination and self-assembly between enantiomers of the same chirality on a supramolecular level has never been reported to date. We investigated the dielectric properties of the compounds prepared in this thesis. Compounds 1 and 4 were found to be third generation low-κ dielectric materials. The dielectric constant (κ = 2.53 at 1 MHz) of 1 was found to be comparable to zeolitic imidazolate frameworks (ZIFs). Its unique anion controlled dielectric behavior is demonstrated for the first time, in which the dielectric constant increases with increasing polarization of the anion. In addition, compound 1 was found to be a good luminescent material (with a green emission at 546 nm) and a modest non-linear optical material in which the second harmonic generation (SHG) efficiency was about twice that of SiO2. Remarkably, the κ value of compound 4 was found to be even lower than the reported ZIFs, owing to the presence of an interlayer free space and the absence of guest molecules. It is a very useful low-κ dielectric material which is highly thermally stable. Frequency dependent dielectric studies for compounds 7 and 8 revealed a significant difference in the value of dielectric constant (κ) and dielectric loss for the two compounds owing to differences in structure and the type of solvent molecules. This fundamental, structure-based study provides insights into the creation of both high and low-κ materials with the judicious selection of guest molecules.Contents ii Abstract xii Chapter 1. Introduction 1 1.1 Self-assembly of metal-organic frameworks (MOFs) 1 1.2 Basics of Dielectrics 8 1.2.1 Types of Polarization Mechanisms in Dielectrics 9 1.2.2 Dielectric Relaxation or Variation of Frequency on the Polarization Mechanisms 10 1.2.3 Types of Dielectric Materials 11 1.2.4 Application of Dielectrics 12 1.2.5 Suitability of MOFs as Dielectric Materials 16 1.3 Synthesis of Chiral Metal-Organic Frameworks 22 1.4 Research Motivation 26 1.5 References 27 Chapter 2. Materials and Methods 30 2.1 Experimental Methods 30 2.2 Characterization Methods 31 2.3 References 42 Chapter 3. Anion Controlled Dielectric Behavior of Homochiral Tryptophan-Based Metal-Organic Frameworks 43 3.1 Introduction 43 3.2 Experimental Section 43 3.3 Results and Discussion 45 3.4 Conclusion 59 3.5 References 59 Chapter 4. Zn-based Chiral Metal-Organic Framework Exhibiting Ultra Low-k Dielectric Properties 61 4.1 Introduction 61 4.2 Experimental Section 61 4.3 Results and Discussion 62 4.4 Conclusion 67 4.5 References 67 Chapter 5. Direction-Selective Arrays of Metal-Organic Rods Triggered by Guest Molecules: Towards a Low-κ Dielectric and Magnetic Material 69 5.1 Introduction 69 5.2 Experimental Section 70 5.3 Results and Discussion 71 5.4 Conclusion 79 5.5 References 79 Chapter 6. Towards the Design of a Robust and Low Dielectric Magnesium(II)−Organic Framework with a cds-Type Topology 83 6.1 Introduction 83 6.2 Experimental Section 83 6.3 Results and Discussion 85 6.4 Conclusion 90 6.5 References 91 Chapter 7. Guest dependent dielectric properties of nickel(II)-based supramolecular networks 96 7.1 Introduction 96 7.2 Experimental Section 97 7.3 Results and Discussion 99 7.4 Conclusion 108 7.5 References 108 Chapter 8: Chiral Discrimination of Metal-Organic Propellers: A Unique Capsule for Rare Water Tetramer 113 8.1 Introduction 113 8.2 Experimental Section 114 8.3 Results and Discussion 115 8.4 Conclusion 121 8.5 References 122 Chapter 9: Conclusion 125 Addendum I: Crystal data and structure refinement 12814427489 bytesapplication/pdf論文公開時間：2017/07/14論文使用權限：同意有償授權(權利金給回饋學校)有機配位化合物蜂巢thesishttp://ntur.lib.ntu.edu.tw/bitstream/246246/261275/1/ntu-103-D98223137-1.pdf