2014-08-012024-05-17https://scholars.lib.ntu.edu.tw/handle/123456789/693893摘要：自旋電子學於近二十年來蓬勃發展，其基礎科學與應用之相關研究為數眾多，而在延長自旋鬆弛時間、提升裝置彈性與自由度的過程中，有機分子展現其極佳之適用性，適當之材料選擇即可組成具備以上特性之系統，而此種金屬-有機系統之界面特性於系統電性與磁性又影響重大。基於我們對有機分子於金屬基板成長之紮實經驗，本計劃期望透過自旋極化掃描穿隧電子顯微鏡及能譜，圖像化金屬-有機介面之微觀自旋態並加以解析。此外，金屬-有機有序混成結構亦提供我們對於金屬與有機材料電荷與自旋轉移現象之了解。藉由對界面行為有系統的研究，本計劃可提供有機自旋電子學更可信賴之發展方向。 <br> Abstract: In the last decades, spintronics has become a huge playground for scientists to develop new fundamental knowledge and applications. During the pursuit of longer spin information preservation and flexibility of devices, organic molecules show their advantages in spintronics. By choosing appropriate organic and inorganic materials, fabrications of systems containing these important functions can be achieved. In this project, we propose to use spin-polarized scanning tunneling microscopy (SP-STM) and spectroscopy (SP-STS) to resolve local spin information below nanoscale in metal-organic systems. Interfacial interactions between molecules and metals, which are vital for electronic and magnetic states of the systems, can be directly imaged and analyzed with SP-STM. Our successful preparations of molecules on metal substrates and metal-organic coordination provide two prototypes for investigations. Through our research on different systems, a more comprehensive understanding of metal-organic interfaces can be established in the end and assists spintronics to step further.自旋電子學自旋極化掃描穿隧顯微鏡有機分子表面界面薄膜交換耦合spintronicsspin-polarized scanning tunneling microscopyorganic moleculessurfaceinterfacefilmsexchange coupling