謝國煌2006-07-262018-06-292006-07-262018-06-292004-07-31http://ntur.lib.ntu.edu.tw//handle/246246/16306反應稀釋單體為具有丙烯酸基的單體，是改變紫外線硬化樹脂的性質，及降低其黏度之目的。胺脂-壓克力寡聚物是理想地結合了聚胺酯的高抗磨耗，韌度，撕裂強度，在低溫的性質，及聚丙烯酸的優越光學性。 本計劃所針對於即時定量複式PCR 檢測樣本載具之應用，合成的寡聚物是以胺基甲酸酯(urethane)與壓克力系(acrylate)單體所合成出，並探討紫外線硬化樹脂中寡聚物/稀釋用之單體的組成性質，更進一步分析其曝光硬化後基本性質，討論其應用於即時定量複式PCR 檢測樣本載具上之可行性。UV-curable polyurethane(PU)-acrylate are typically composed of reactive urethaneacrylate oligomers, reactive diluents, and photoinitiators. The reactive urethane-acrylate oligomers are prepared by reacting polyols with excess diisocyanates and end-capping with hydroxyalkyl acrylate or methacrylate. The reactive diluents are acrylate monomers which are added to modify the properties and to reduce the viscosity of the UV-curable resin. The urethane acrylate ideally combine the high abrasion resistance, toughness, tear strength, and good low temperature properties of PU with the superior optical properties of polyacrylates. UV-curable reactive urethane-acrylate oligomers for Multiplex Real Time PCR machine’s specimen vehicle will be synthesized in this study. The compositions of the oligomer/diluent on the properties of the UV-curable urethane-acrylate will be investigated. Further analyses of film properties after exposure and the capabilities as a sample vehicle utilized on Multiplex Real Time PCR Machine will be investigated.application/pdf390506 bytesapplication/pdfzh-TW國立臺灣大學高分子科學與工程學研究所紫外線硬化樹脂寡聚物反應性單體UV-curable resinoligomerreactive diluentsreporthttp://ntur.lib.ntu.edu.tw/bitstream/246246/16306/1/922218E002047.pdf