2017-01-012024-05-15https://scholars.lib.ntu.edu.tw/handle/123456789/665660摘要：由於目前大多數的HMF之氧化反應皆在高溫高壓的嚴苛環境條件下進行，且HMF轉化率及FDCA選擇率和產率並不高。本實驗將結合中研院在基礎科學上的優勢，以及台大化工系在製程優化及放大上的實力，開發以液相氧氣源 (H2O2、t-BuOOH…) 作為氧化劑，並且利用新穎技術合成metals-loaded MOFs-derived 奈米碳材作為觸媒，用於HMF轉化成FDCA的綠色製程開發。此技術優點為便宜及反應後副產物為水，不會對環境造成危害，符合環保概念；而且若觸媒能催化氧化反應之進行，可降低反應時的溫度和壓力，並且異相催化劑可回收並重複利用，能節省反應的成本，計畫願景為開發一個具有綠能製程及永續性之FDA之工業化生產觸媒及程序。<br> Abstract: 5-Hydroxymethylfurfural (HMF) is a lignocellulosic-derived compound that can be a platform converting into many valuable compounds. Containing a hydroxyl group, an aldehyde group, and a ring structure, HMF via the aerobic oxidation could be converted to several useful compounds such as levulinic acid (ring-opening)1, 2,5-dimethylfuran (hydrogenolysis)2, and 2,5-furandicarboxylic acid (oxidation) as shown in Fig. 1. Recently, the aerobic oxidation of HMF has received great attention since the final product, 2,5-furandicarboxlic acid (FDCA), is a renewable building block chemical with the potential of replacing terephthalic acid to be the monomer in plastic manufacturing.5-羥甲基糠醛25-&#21579喃二甲酸金屬奈米孔洞碳材5-Hydroxymethylfurfural2,5-furandicarboxylic acid (FDCA)Metal-loaded Nanoporous Carbon