理學院: 化學研究所指導教授: 邱勝賢吳翌瑋Wu, Yi-WeiYi-WeiWu2017-03-022018-07-102017-03-022018-07-102015http://ntur.lib.ntu.edu.tw//handle/246246/272040利用鈉離子模版引導雙胺分子及四醛分子形成動態亞胺鍵，藉此自組裝成環狀[2]交環烷二聚體、三聚體和四聚體。利用氫硼化鈉還原不穩定的亞胺鍵，接著對二級胺進行甲基化反應，經由分離得到全部由共價鍵建構之環狀[2]交環烷寡聚體，並鑑定其結構。Dimeric, trimeric, and tetrameric cyclic [2]catenanes were assembled directly from an one-pot Na+ ion-templated dynamic imine formation from suitable diamines and tetraaldehydes. Using NaBH4 to reduce the labile imono bonds of the cyclic [2]catenane oligomers, followed by methylation of the resulting secondary amines, allowed the isolation and characterization of these oligomeric cyclic [2]catenanes as stable covalently linked compounds.5040904 bytesapplication/pdf論文公開時間: 2025/12/20論文使用權限: 同意有償授權(權利金給回饋學校)自組裝交環烷寡聚體Self-AssemblyCatenaneOligomersthesishttp://ntur.lib.ntu.edu.tw/bitstream/246246/272040/1/ntu-104-R02223129-1.pdf