蔣本基2006-07-262018-06-282006-07-262018-06-281999-07-31http://ntur.lib.ntu.edu.tw//handle/246246/22020本研究主要探討不同材質活性碳 (Sorbonorit 3、Norit RB 3、Norit RX 3 extra、 Norit RBAA 3、Darco Vapure、Filtrasorb 100、 Filtrasorb 400、Unicarb)之物化特性對不同化 學性質之毒性空氣污染物吸附作用之影響。 研究選用不同材質的活性碳，同時以危害性 空氣活染物(HAPs)為對象，期能藉由活性碳 基礎物化特性和吸附質化學性質的瞭解、環 境因子的控制、以及吸附現象的探討，獲得 其建設性之成果。其研究目的即欲瞭解活性 碳物化特性，評估其對揮發性有機平衡吸附 量之影響，並提出吸附模式參數之特性方程 式，以有效預估平衡吸附量。The objectives of this research were focused on understanding the interactions between activated carbons (Sorbonorit 3、Norit RB 3、Norit RX 3 extra、Norit RBAA 3、Darco Vapure、Filtrasorb 100、Filtrasorb 400、Unicarb) and hazardous air pollutants (HAPs) with various functional groups. The relationship between the physico-chemical characterizations of activated carbons and the adsorptive capacities for hazardous air pollutants are also investigated. Moreover, the introduced model would be validated through use of the column experiment. The results of this research were first to determine the principal physicochemical properties of activated carbon affected the adsorption capacity. Subsequently, a characteristic equation for calculating the equilibrium constant was developed to predict the VOC adsorption capacity on activated carbon. Finally, a kinetic model was introduced to determine the respective parameters associated with adsorption / desorption processes.application/pdf89651 bytesapplication/pdfzh-TW國立臺灣大學環境工程學研究所活性碳危害性空氣污染物物化特性官能基等溫吸附模式Activated CarbonHazardous Air PollutantsPhysico-Chemical CharacterizationFunctional GroupsAdsorptive Mechanism[SDGs]SDG11reporthttp://ntur.lib.ntu.edu.tw/bitstream/246246/22020/1/882211E002003.pdf