2017-06-012024-05-18https://scholars.lib.ntu.edu.tw/handle/123456789/705243摘要：隨著人口的增長及文明的進步，人均使用水量及總使用量均與日俱增。再者由於溫室效應導致全球氣候異常，在降雨量分布不均及新水源難覓的情況下，淡水資源儼然已是二十一世紀之人類最重要問題之一。本研究計畫—以循環碳材製備電容去離子法(capacitive deionization（CDI)）元件來處理海水淨化成淡水—由三個學術單位包括交通大學材料所、交通大學電子所及台大環工所和一個產業界公司—和淞科技股份有限公司—共同進行。 首先由交通大學材料科學與工程學系所韋光華教授團隊處理從回收碳鋅電池之碳電極（循環碳材），將其以本實驗室開發之台灣及美國專利技術—陰極電漿電化學剝離法—量產出石墨烯奈米片，再將其經由高分子微球模板法燒解，製出多孔洞石墨烯奈米片，且進行表面 、型態 、比表面積及孔洞等分析以期達成應用需求。所產之多孔洞石墨烯奈米片再經由電子工程系所曾俊元教授團隊進行製出多孔洞石墨烯奈米片及二氧化錳複合電極，且進行電化學分析量測所製備電極，以期能達成多孔洞電極之條件。最後由台大環境工程學研究所侯嘉洪教授團隊進行CDI元件開發及其淨水效能之量測及整個元件之最佳化，並針對不同水源調整元件設計。三個研究團隊在個自負責領域均有多年專業經驗而和淞公司亦多年支持石墨烯奈米片開發。<br> Abstract: Owing to the rapidly increasing world population, advancing civilization and dramatic climate changes, the need for human being to obtain drinkable water resources become more urgent than ever. This project involves using carbon materials that had been taken from recycled batteries as the precursors for fabricating capacitive deionization (CDI) water-purifying devices, and will be carried out by a collaboration of three institutions—National Chiao Tung University (NCTU), department of materials science and engineering (MSE) and department of electronics engineering (EE) and National Taiwan University (NTU), Environmental enginnering institute (EEI) and one company—Taiwan Puritic Corp. First, Prof. Wei’s group form MSE, NCTU will carry out plasma-assisted electrochemical exfoliation of carbon electrodes from recycled batteries for producing graphene nanosheets with their invented Taiwan and US patents, and then incorporate polymer microspheres into the graphene nanosheets for undergoing thermal treatments to produce mesoporous graphene nanosheets. Second, prof. Tseng’s group from EE, NCTU will combine produced mesoporous graphene nanosheets with MnO2 for making composite electrodes that are needed for CDI water-purifying devices, and analyze the electrochemical properties of the composite electrodes for optimizing their performances. Last, Prof. Huo from EEI, NTU will perform the fabrication of various CDI devices with the composite electrodes and test the CDI devices with various water sources. All three groups have their dedicated research expertise—graphene nanosheets, electrochemical analyses and CDI devices fabrication—in this project. The company that is involved in this project has been supporting the graphene nanosheets research for a few years. We plan to demonstrate these CDI devices that will be fabricated with our matertials and processes at the end of this project.水淨化回收碳棒氧化石墨烯石墨烯氣凝膠電漿剝落電容去離子化water purificationrecycle graphite rodsgraphene nanosheetsaerogelplasma exfoliationcapacitive deionization