Chen C.-WTIEN-YAU LUH2022-12-142022-12-14200800223263https://www.scopus.com/inward/record.uri?eid=2-s2.0-55249121165&doi=10.1021%2fjo8013885&partnerID=40&md5=3181907db970b553b385023ca44a1db7https://scholars.lib.ntu.edu.tw/handle/123456789/626263(Chemical Equation Presented) Treatment of propargylic dithiolanes 1 with nBuLi followed by a carbonyl electrophile yields the corresponding homopropargylic alcohol 3. Upon treatment with 2 equiv of PPh3 and DIAD, elimination of SR and OH moieties from 3 affords the corresponding olefins 4 in moderate to good yield. The reaction can be considered an alternative of McMurry coupling of two different carbonyl equivalents. © 2008 American Chemical Society.[SDGs]SDG6Carbonylation; Chemical reactions; Olefins; Chemical equations; Conjugated enynes; Dithioacetals; Dithiolanes; Electrophile; Good yields; Homopropargylic alcohols; Mitsunobu conditions; Synthesis of; Organic polymers; acetal derivative; alcohol derivative; alkene derivative; carbonyl derivative; thiol derivative; article; chemical reaction; chemical structure; elimination reaction; Mitsunobu reaction; quantum yield; reaction analysis; stereospecificity; synthesisjournal article10.1021/jo80138852-s2.0-55249121165