何國川2006-07-252018-06-282006-07-252018-06-282001http://ntur.lib.ntu.edu.tw//handle/246246/9270The plating solution's stability and the electrodeposition for indium hexacyanoferrate(InHCF), an important analogue of Prussian blue(PB), were greatly ebhanced by adding a large amount of K+ and/or H+. It was found that a 10-mM plating solution added with 1N HCl and 1N KCl could be stored as a fresh one over a week, whereas an unmodified plating solution became useless within couples of minutes. Moreover, the InHCF film grown in an H+-rich environment showed comparatively higher cycle ability, based on the results of electrochemical characterizations. Besides, related enhanced mechanisms were proposed and verified, To sum up, this work has provided a means for better electrodeposition of PD analogues.application/pdf273694 bytesapplication/pdfzh-TW國立臺灣大學化學工程學系暨研究所electrochromicindium hexacyano-ferratePussian bluereporthttp://ntur.lib.ntu.edu.tw/bitstream/246246/9270/1/892214E002072.pdf