Yi-Zhen LiHsuan-Chi LiangChia-Hsun ChenChing-Huang ChiuLian-Chun HuangYi-Ting LeeYi-Chung DzengChi ChenBo-Yen LinJiun-Haw LeeTien-Lung ChiuMAN-KIT LEUNG2024-10-092024-10-092024-10https://scholars.lib.ntu.edu.tw/handle/123456789/721927An appropriate host featuring a wide band gap (Eg) and high triplet energy (T1) is crucial for facilitating highly efficient blue-light emitting devices. In this study, 4Ac26CzBz, a new host comprising acridan and carbazole moieties linked to a benzimidazole core, has been synthesized and characterized. Notedly, 4Ac26CzBz exhibits a wide optical gap (Eg) and high triplet energy (T1) of 3.3 and 3.0 eV, respectively, and has been proven a suitable host for blue thermally activated delayed fluorescence (TADF) OLED. By adopting 4TCzBN as a blue-light dopant, a remarkably high device external quantum efficiency of 35.8 % (59.8 cd/A and 62.8 lm/W) and a low turn-on voltage (<3 eV) have been demonstrated, with significant suppression of the efficiency roll-off, maintaining a high efficiency of 29.7 % as luminance at 1000 cd/m2. This excellent performance is deduced from the host's ambipolar carrier transporting properties, which refer to its ability to transport both electrons and holes effectively, high photoluminescence quantum yield (PLQY) of 98.6 %, and highly horizontal orientation of transition dipole, as determined through diverse analytical measurements. The good material properties of 4Ac26CzBz and the high OLED performance reveal its potential for the next generation's advanced display and lighting applications.enAcridanBlue TADF OLEDHost materialsLow driving voltagejournal article10.1016/j.cej.2024.155553