Hydrogenolysis without hydrogen gas: Hydrogen loaded palladium electrodes by electrolysis of H[NTf2] in a room temperature ionic liquid

Meng, YaoYaoMengLEIGH ALDOUSCompton, Richard G.Richard G.Compton2024-09-182024-09-182010https://www.scopus.com/record/display.uri?eid=2-s2.0-78049359718&origin=resultslisthttps://scholars.lib.ntu.edu.tw/handle/123456789/721085Electrochemical hydrogenolysis has been demonstrated in a room temperature ionic liquid (RTIL) for the first time. Reduction of H[NTf2] at a Pd microelectrode in the RTIL 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C2mim][NTf2]) leads to the reversible formation of adsorbed and absorbed hydrogen (Pd/H). Hydrogenation of N, N′-bis(benzyloxycarbonyl)-L-lysine was observed to proceed rapidly, monitored by the consumption of Pd/H. In addition, the electrolysis of adventitious H2O to form Pd/H is noted. © 2010 The Royal Society of Chemistry.[SDGs]SDG6Hydrogenolysis without hydrogen gas: Hydrogen loaded palladium electrodes by electrolysis of H[NTf2] in a room temperature ionic liquidjournal article10.1039/c0gc00450b2-s2.0-78049359718