李克強2006-07-252018-06-282006-07-252018-06-282000http://ntur.lib.ntu.edu.tw//handle/246246/9234The sedimentation behavior of a concentrated suspension of charged spherical particles is investigated theoretically. The sedimentation potential is evaluated taking the effect of double layer polarization into account. A cell model is adopted to describe thepresent multientities system, and a pseudo-spectral numerical scheme is used to solve the governing electrokinetic equations, which comprise a Navior-Stoked equation for flow field and a Poisson equation for electric field. Several interesting phenomena, which are absent if double layer polarization is neglected, are observed. For example, the atio(E*/U*), E* and U* being respectively the scaled sedimentation potential has a minimum if the electrical potential is low, and has a maximum if it is high.本研究為了解帶電密集膠體溶液之沈降理論,在本研究中考慮了電集層橿化效應,使用細胞模式來描述多顆粒子之系統,使用假光譜法來求解主控電動方程式,其中有流場之Navior-Stokes方程式,電場之Poisson方程式,發現了一些有趣的現象,如沈降電位在表面電位小時有最小值,而在表面電位大時有最大值。application/pdf653999 bytesapplication/pdfzh-TW國立臺灣大學化學工程學系暨研究所電泳電位電集層極化懸浮溶液密集膠體球形粒子中之沈降電位探討Sedimentation potential of a concentrated spherical colloidal suspensionreporthttp://ntur.lib.ntu.edu.tw/bitstream/246246/9234/1/892214E002003.pdf