https://scholars.lib.ntu.edu.tw/handle/123456789/178743
Title: | 萘啶胺衍生物配基及其直線型四核鎳金屬錯合物之成、構造與物理性質研究 Synthesis, Crystal Structures and Physical Properties of Series of Linear Tetranickle Complexes with he Naphthyridine-Functionalized Amine Ligands |
Authors: | 葉哲維 Yeh, Che-Wei |
Keywords: | 萘啶胺衍生物配基;直線型四核鎳金屬錯合物;Naphthyridine-Functionalized Amine Ligands;Linear Tetranickle Complexes | Issue Date: | 2008 | Abstract: | 本論文是探討以萘啶胺 (H2any) 衍生物配基,吡啶萘啶胺(Hpyany),萘啶甲基醯胺 (Hnyma) 與金屬形成錯合物之合成、構造與物理性質研究。本研究合成出三種不同形式之金屬錯合物,將分別於不同章節做介紹與探討。 首先利用四氮配基吡啶萘啶胺和磺醯甲苯基二吡啶二胺 (H2Tsdpda) 合成出ㄧ系列之混配基四核鎳 (Ni) 金屬串錯合物,錯合物[Ni4( Three types of metal complexes with naphthyridine-functionalized amine ligands, 2-α-pyridylamino-1,8-naphthyridine (Hpyany) and N-1,8-naphthyridyl methylamide (Hnyma) have been prepared. irst, a series of linear tetranickel complexes coordinated by two kinds of ligands, Hpyany and p-toluenesulfonyl di-pyridyl-di-amine (H2Tsdpda), have been synthesized. Their structures were determined by single-crystal X-ray diffraction analysis. The ligands, Hpyany and H2Tsdpda, have been deprotonated to act as tetradentate ligands and helically wrapped the nickel metal ions to form a tetranuclear metal string, which is structurally similar to the previous report. The molecular structure of the one-electron reduction species [Ni4( |
URI: | http://ntur.lib.ntu.edu.tw//handle/246246/187440 |
Appears in Collections: | 化學系 |
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ntu-97-R95223020-1.pdf | 23.32 kB | Adobe PDF | View/Open |
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