https://scholars.lib.ntu.edu.tw/handle/123456789/630147
Title: | Effect of the length of bromoalkyl chains on light-driven hydrogen evolution facilitated by fluorene-based polymers | Authors: | Sun, Han Sheng Tsai, Tien Liang Chang, Cheng Hao Chen, Yen Yu Yang, Hau Ren JEFFREY CHI-SHENG WU YU-YING LAI |
Keywords: | GRAPHITIC CARBON NITRIDE; NITROGEN-DOPED GRAPHENE; CONJUGATED POLYMERS; H-2 EVOLUTION; PHOTOCATALYSTS; NANOPARTICLES; OXIDE | Issue Date: | 7-Sep-2022 | Publisher: | ROYAL SOC CHEMISTRY | Journal Volume: | 6 | Journal Issue: | 19 | Start page/Pages: | 4470 | Source: | Sustainable Energy and Fuels | Abstract: | Six fluorene-based polymers are designed, synthesized, characterized, and examined in light-driven hydrogen evolution. The relationship of the hydrogen-evolution activity with the optical/electronic characteristics of the polymers is insignificant, suggesting that it might not be the most crucial factor in distinguishing the efficiency. Polymers with shorter bromoalkyl chains exhibit greater hydrogen evolution rates (HERs) than their analogues with longer chains, highlighting the significance of chain length in the reaction. The role of residual Pd as a co-catalyst is investigated. The HER is improved substantially by the presence of Pd. A high HER of 42 mmol g−1 h−1, which is among the highest reported to date, has been achieved. Overall, this work demonstrates that side-chain truncation and modification serve as a straightforward approach to improving the hydrogen-evolution activity. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/630147 | ISSN: | 2398-4902 | DOI: | 10.1039/d2se00902a |
Appears in Collections: | 高分子科學與工程學研究所 |
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