Pronounced effects of counterions on intramolecular electron transfer in 1′, 1‴-dinaphthylmethylbiferrocenium cation
Journal
Inorganic Chemistry Communications
Journal Volume
4
Journal Issue
2
Pages
82-85
Date Issued
2001
Author(s)
Abstract
The X-ray structure of 1′, 1‴-dinaphthylmethylbiferrocenium BF4 has been determined. The 57Fe Mössbauer and EPR results of 1′, 1‴-dinaphthylmethylbiferrocenium BF4 and PF6 salts are also reported. The relatively minor perturbations caused by the counterions have pronounced effects on the rate of intramolecular electron transfer. © 2001 Elsevier Science B.V.
Subjects
Biferrocenium; Electron transfer; Metallocene; Mixed-valence 1′, 1‴-dinaphthylmethylbiferrocenium
Other Subjects
ferrocene derivative; fluorine derivative; iron 57; methyl group; naphthyl group; article; chemical bond; chemical interaction; crystal structure; electron spin resonance; electron transport; Mossbauer spectroscopy
Type
journal article