https://scholars.lib.ntu.edu.tw/handle/123456789/626336
標題: | Pronounced effects of counterions on intramolecular electron transfer in 1′, 1‴-dinaphthylmethylbiferrocenium cation | 作者: | Dong T.-Y Lee T.-J Huang B.-R SHIE-MING PENG Lee G.-H. |
關鍵字: | Biferrocenium; Electron transfer; Metallocene; Mixed-valence 1′, 1‴-dinaphthylmethylbiferrocenium | 公開日期: | 2001 | 卷: | 4 | 期: | 2 | 起(迄)頁: | 82-85 | 來源出版物: | Inorganic Chemistry Communications | 摘要: | The X-ray structure of 1′, 1‴-dinaphthylmethylbiferrocenium BF4 has been determined. The 57Fe Mössbauer and EPR results of 1′, 1‴-dinaphthylmethylbiferrocenium BF4 and PF6 salts are also reported. The relatively minor perturbations caused by the counterions have pronounced effects on the rate of intramolecular electron transfer. © 2001 Elsevier Science B.V. |
URI: | https://www.scopus.com/inward/record.uri?eid=2-s2.0-0035147371&doi=10.1016%2fS1387-7003%2800%2900212-4&partnerID=40&md5=c334e60daf2198c1d957268e36bc3a9c https://scholars.lib.ntu.edu.tw/handle/123456789/626336 |
ISSN: | 13877003 | DOI: | 10.1016/S1387-7003(00)00212-4 | SDG/關鍵字: | ferrocene derivative; fluorine derivative; iron 57; methyl group; naphthyl group; article; chemical bond; chemical interaction; crystal structure; electron spin resonance; electron transport; Mossbauer spectroscopy |
顯示於: | 化學系 |
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