https://scholars.lib.ntu.edu.tw/handle/123456789/350127
標題: | Performance enhancement of organic/inorganic hybrid solar cells by improving the optical absorption of polymer | 作者: | Huang, J.-S. Chou, C.-Y. Liu, M.-Y. Wu, C.-H. Lin, Y.-H. Lin, W.-H. CHING-FUH LIN |
關鍵字: | Fullerene; Optical absorption; Organic/inorganic hybrid solar cell; Slow drying; ZnO nanorod | 公開日期: | 2009 | 卷: | 7416 | 來源出版物: | Proceedings of SPIE - The International Society for Optical Engineering | 摘要: | The performance of the polymer/ZnO nanorod hybrid solar cells based on poly(3-hexylthiophene) and methanofullerenes is improved with the enhanced optical absorption by increasing the thickness of the photoactive layer and introducing a solution-processed interlayer. The dependence of the optical absorption on the thickness of the photoactive layer is studied as a function of the spin-coating rate. With the slower spin-coating rate, the photoactive layer is thicker, and the polymer chains have longer time to self-organize and more effectively infiltrate into ZnO nanorod spacing. In addition, a solution-processed fullerene interlayer is introduced to modify the ZnO nanorod surface. With this interlayer, the optical absorption of the photoactive layer increases due to the better ordering of the photoactive layer. Our investigations show that the power conversion efficiency (PCE) is improved from 1.6% to 2.6% with the thickness of the photoactive layer from 240 nm to 350 nm by slowing the spin coating rate of the photoactive layer. Moreover, the PCE is also improved by the fullerene interlayer. The slow-drying method and the solution-processed fullerene interlayer both improve the crystallinity of the polymer and light harvesting. © 2009 SPIE. |
URI: | http://www.scopus.com/inward/record.url?eid=2-s2.0-70449578492&partnerID=MN8TOARS http://scholars.lib.ntu.edu.tw/handle/123456789/350127 |
DOI: | 10.1117/12.825970 | SDG/關鍵字: | Crystallinities; Drying methods; Hybrid solar cells; Light-harvesting; Methanofullerenes; Optical absorption; Organic/inorganic hybrid solar cell; Organic/Inorganic hybrids; Performance enhancements; Photoactive layers; Poly (3-hexylthiophene); Polymer chains; Power conversion efficiencies; Self-organize; Slow drying; Solution-processed; ZnO nanorod; Absorption; Conversion efficiency; Dewatering; Fullerenes; Light absorption; Nanorods; Photovoltaic cells; Photovoltaic effects; Plastic coatings; Polymers; Semiconducting zinc compounds; Spin dynamics; Zinc oxide; Solar cells |
顯示於: | 電機工程學系 |
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