https://scholars.lib.ntu.edu.tw/handle/123456789/407979
標題: | Adsorption-desorption of strontium from waters using aerobic granules | 作者: | Wang L. Wan C. Lee D.-J. Tay J.-H. Chen X.F. Liu X. Zhang Y. |
關鍵字: | Adsorption;Desorption;Feasibility;Kinetics | 公開日期: | 2013 | 卷: | 44 | 期: | 3 | 起(迄)頁: | 454-457 | 來源出版物: | Journal of the Taiwan Institute of Chemical Engineers | 摘要: | Adsorption of Sr(II) from waters is regarded a unit operation to remediate nuclear contaminations in aquatic systems. Aerobic granules were applied as a biosorbent for removing Sr(II) from waters. At pH 6.2 and 35. ¢XC the adsorption can reach equilibrium within 2. h while the maximum adsorption capacity was estimated as 28.8. mg/g dried biomass. Kinetic model fitting suggested that the pseudo-second-order model best correlated the kinetic data, suggesting that chemical adsorption was the rate-limiting step. Repeated adsorption and then desorption with water, K(I), Na(I) and Ca(II) desorbents suggested that neither water alone or Ca(II) could effectively desorb Sr(II) from the aerobic granule surface. Conversely, Na(I) and K(I) could effectively complex with the functional groups on polysaccharides in the extracellular polymeric substance so could effectively desorb the bound Sr(II) out of the granule surface. ? 2012 Taiwan Institute of Chemical Engineers. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/407979 | ISSN: | 18761070 | DOI: | 10.1016/j.jtice.2012.12.005 |
顯示於: | 化學工程學系 |
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