https://scholars.lib.ntu.edu.tw/handle/123456789/408919
標題: | Comparison of objective functions for batch crystallization using a simple process model and Pontryagin's minimum principle | 作者: | Tseng Y.-T. Ward J.D. |
關鍵字: | Batch crystallization;Optimal control theory;Pontryagin's minimum principle | 公開日期: | 2017 | 卷: | 99 | 起(迄)頁: | 271-279 | 來源出版物: | Computers and Chemical Engineering | 摘要: | In this contribution different objective functions based on the moments of the product crystal size distribution are compared using optimal control theory to solve for the optimal batch trajectory for each objective. For a simple crystallization process model with only nucleation and ordinary crystal growth, and neglecting the contribution of the nucleated mass to the nucleation rate and material balance, mostly analytic expressions are obtained for the optimal control vector. Different objective functions lead to different final values for the costates, which lead to different sets of coupled differential and algebraic equations which must be solved to determine the values of constants numerically. The results of nine different objective functions for three crystal systems are presented. The objective functions based on the lower moment of the nucleated crystals lead to late-growth trajectories while the objective functions based on the higher moment of the nucleated crystals lead to early-growth trajectories, consistent with previous findings. The effect of seed loading is also investigated. ? 2017 Elsevier Ltd |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/408919 | ISSN: | 00981354 | DOI: | 10.1016/j.compchemeng.2017.01.017 |
顯示於: | 化學工程學系 |
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