https://scholars.lib.ntu.edu.tw/handle/123456789/425023
標題: | Microstructural design of silicon nitride with improved fracture toughness: II, Effects of yttria and alumina additives | 作者: | Sun E.Y. Becher P.F. Plucknett K.P. Hsueh C.-H. Alexander K.B. Waters S.B. Hirao K. Brito M.E. CHUN-HWAY HSUEH |
公開日期: | 1998 | 卷: | 81 | 期: | 11 | 起(迄)頁: | 2831-2840 | 來源出版物: | Journal of the American Ceramic Society | 摘要: | Significant improvements in the fracture resistance of self-reinforced silicon nitride ceramics have been obtained by tailoring the chemistry of the intergranular amorphous phase. First, the overall microstructure of the material was controlled by incorporation of a fixed amount of elongated B-Si 3N 4 seeds into the starting powder to regulate the size and fraction of the large reinforcing grains. With controlled microstructures, the interfacial debond strength between the reinforcement and the intergranular glass was optimized by varying the yttria-to-alumina ratio in the sintering additives. It was found that the steady-state fracture toughness value of these silicon nitrides increased with the Y:Al ratio of the oxide additives. The increased toughness was accompanied by a steeply rising R-curve and extensive interfacial debonding between the elongated £]-Si 3N 4 grains and the intergranular glassy phase. Microstructural analyses indicate that the different fracture behavior is related to the Al (and O) content in the £]¡¬-SiAlON growth layer formed on the elongated £]-Si 3N 4 grains during densification. The results imply that the interfacial bond strength is a function of the extent of Al and Si bonding with N and O in the adjoining phases with an abrupt structural/chemical interface achieved by reducing the Al concentration in both the intergranular phase and the £]¡¬-SiAlON growth layer. Analytical modeling revealed that the residual thermal expansion mismatch stress is not a dominant influence on the interfacial fracture behavior when a distinct £]¡¬-SiAlON growth layer forms. It is concluded that the fracture resistance of self-reinforced silicon nitrides can be improved by optimizing the sintering additives employed. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/425023 | ISSN: | 00027820 |
顯示於: | 材料科學與工程學系 |
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