https://scholars.lib.ntu.edu.tw/handle/123456789/425105
標題: | Tuning perovskite morphology by polymer additive for high efficiency solar cell | 作者: | Chang, Chun Yu Chu, Cheng Ya Huang, Yu Ching Huang, Chien Wen Chang, Shuang Yuan Chen, Chien An CHI-YANG CHAO WEI-FANG SU |
關鍵字: | coverage | morphology | perovskite solar cells | polymer additive | solution process | TiO nanoparticle 2 | 公開日期: | 1-一月-2015 | 出版社: | AMER CHEMICAL SOC | 卷: | 7 | 期: | 8 | 起(迄)頁: | 4955 | 來源出版物: | ACS Applied Materials and Interfaces | 摘要: | © 2015 American Chemical Society. Solution processable planar heterojunction perovskite solar cell is a very promising new technology for low cost renewable energy. One of the most common cell structures is FTO/TiO 2 /CH 3 NH 3 PbI 3-x Cl x /spiro-OMeTAD/Au. The main issues of this type of solar cell are the poor coverage and morphology control of the perovskite CH 3 NH 3 PbI 3-x Cl x film on TiO 2 . For the first time, we demonstrate that the problems can be easily resolved by using a polymer additive in perovskite precursor solution during the film formation process. A 25% increase in power conversion efficiency at a value of 13.2% is achieved by adding 1 wt % of poly(ethylene glycol) in the perovskite layer using a 150 °C processed TiO 2 nanoparticle layer. The morphology of this new perovskite was carefully studied by SEM, XRD, and AFM. The results reveal that the additive controls the size and aggregation of perovskite crystals and helps the formation of smooth film over TiO 2 completely. Thus, the V oc and J sc are greatly increased for a high efficiency solar cell. The amount of additive is optimized at 1 wt % due to its insulating characteristics. This research provides a facile way to fabricate a high efficiency perovskite solar cell by the low temperature solution process (<150 °C), which has the advancement of conserving energy over the traditional high temperature sintering TiO 2 compact layer device. |
URI: | https://scholars.lib.ntu.edu.tw/handle/123456789/425105 | ISSN: | 19448244 | DOI: | https://api.elsevier.com/content/abstract/scopus_id/84924227191 10.1021/acsami.5b00052 |
SDG/關鍵字: | Additives; Heterojunctions; Morphology; Nanoparticles; Perovskite; Polyethylene glycols; Polymer solar cells; Sintering; Temperature; TiO2 nanoparticles; Titanium dioxide; coverage; High-efficiency solar cells; High-temperature sintering; Low temperature solutions; Polymer additive; Power conversion efficiencies; Solution process; Solution processable; Perovskite solar cells |
顯示於: | 材料科學與工程學系 |
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