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  4. Materials interaction between Pb-free Sn-9Zn solder and Au pad in advanced electronic packages
 
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Materials interaction between Pb-free Sn-9Zn solder and Au pad in advanced electronic packages

Journal
4th International Symposium on Electronic Materials and Packaging 2002
Pages
324-329
ISBN
078037682X
9780780376823
Date Issued
2002
Author(s)
Lin Y.L.
Tsai J.
C. ROBERT KAO  
DOI
10.1109/EMAP.2002.1188859
URI
https://www.scopus.com/inward/record.uri?eid=2-s2.0-45449117403&doi=10.1109%2fEMAP.2002.1188859&partnerID=40&md5=13ccdaefa49852a2924a8d17cf063067
https://scholars.lib.ntu.edu.tw/handle/123456789/432733
Abstract
At present, the electronic packaging industry is actively searching for Pb-free solders due to environment concern of Pb-based solders. Recently, the European Union had proposed to ban the lead-bearing solders by the year of 2008. Moreover, several major Japanese electronic companies, such as Panasonic and Fujitsu, have decided to switch voluntarily to lead-free processes by the year 2002. Among many potential candidates, Sn9Zn solder is a very promising replacement. In fact, NEC-Panasonic and Toshiba have used this solder in their products. The objective of this study is to investigate the reactions between Sn9Zn solder balls with a common surface finish used in the industry. The Au/Ni surface finish is the most common and important one for solder pads in the industry now. In this study, two kinds of intermetallic compounds were formed at different temperature (240/spl deg/C - AuZn/sub 3/, 250/spl deg/C - AuSn/sub 4/). When the reaction between pure Au (50 /spl mu/m) and Sn9Zn, with short reflow time (1 min) at 240/spl deg/C, a lot of Au-Zn intermetallic compounds formed at the solder ball and a thin layer of Au-Sn intermetallic compounds formed at the interface. With the reaction time increasing, intermetallic compounds changed from Au-Zn to Au-Zn-Sn. Finally, the Au-Zn-Sn intermetallic compounds were formed completely. During the Sn9Zn reaction with pure Au (50 /spl mu/m) at 250/spl deg/C, a small amount of Au-Zn intermetallic compounds are also formed for a short time (1 min). Finally, they changed to Au-Zn-Sn intermetallic compounds completely.
SDGs

[SDGs]SDG9

Publisher
Institute of Electrical and Electronics Engineers Inc.
Type
conference paper

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