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  4. Use of 2-(6-mercaptohexyl) malonic acid to adjust the morphology and electret properties of cyclic olefin copolymer and its application to flexible loudspeakers
 
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Use of 2-(6-mercaptohexyl) malonic acid to adjust the morphology and electret properties of cyclic olefin copolymer and its application to flexible loudspeakers

Journal
Smart Materials and Structures
Journal Volume
19
Journal Issue
5
Date Issued
2010
Author(s)
Ko, W.-C.
Tseng, C.-K.
Leu, I.-Y.
Wu, W.-J.
Lee, A.S.-Y.
WEN-JONG WU  
CHIH-KUNG LEE  
DOI
10.1088/0964-1726/19/5/055007
URI
https://scholars.lib.ntu.edu.tw/handle/123456789/452025
URL
https://www.scopus.com/inward/record.uri?eid=2-s2.0-77951251040&doi=10.1088%2f0964-1726%2f19%2f5%2f055007&partnerID=40&md5=cbdaa0b1e309fb811732dc9fe424c542
Abstract
Recent uses of flexible electret loudspeakers in futuristic applications have garnered much interest for these novel loudspeakers. In this paper, a novel thin film processing method was developed to improve the performance of an electret diaphragm. This paper discusses the relationship between the charge storage and the additive concentration. A cyclic olefin copolymer (COC) thin film containing an additive such as 2-(6-mercaptohexyl) malonic acid was prepared using a spin-coating process. Furthermore, attention was directed towards the processing conditions which were found to have an important role and are related to the self-assembly and micelle formation behavior of the additives in the COC. In the present study, thin films of 13 νm thickness were charged by a corona method. Compared with a reference thin film of pure COC, results indicated that when a 3497 mgkg -1 additive was added to the COC matrix, the obtained surface potential was 71% higher. Thus, the results show that a COC + additive thin film leads to a much improved charge storage. It appears to be an inexpensive and relatively easy way to form a thin structure for developing novel flexible electret loudspeakers.
Type
journal article

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