Large AuAg Alloy Nanoparticles Synthesized in Organic Media Using a One-Pot Reaction: Their Applications for High-Performance Bulk Heterojunction Solar Cells
Journal
Advanced Functional Materials
Journal Volume
22
Journal Issue
19
Pages
3975-3984
Date Issued
2012
Author(s)
Chen, Hsieh-Chih
Chou, Shang-Wei
Tseng, Wei-Hsuan
Chen, I.-Wen P.
Liu, Chi-Chang
Liu, Chun
Liu, Chien-Liang
Chen, Chun-Hsien
Wu, Chih-I.
Abstract
Abstract A one?pot synthesis of large size and high quality AuAg alloy nanoparticles (NPs) with well controlled compositions via hot organic media is demonstrated. Amid the synthesis, complexation between trioctylphosphine (TOP) and metal precursors is found, which slows down the rate of nucleation and leads to the growth of large?size AuAg nanoalloys. The wavelength and relative intensities of the resulting plasmon bands are readily fine?tuned during the synthetic process using different Au/Ag precursors molar ratios. In the polymer solar cells, a key step in achieving high efficiency is the utilization of 1% Au 11 Ag 89 alloy NPs embedded in the active layer to promote the power conversion efficiency (PCE) up to 4.73%, which outperforms the reference device based on the control standard device of poly(3?hexylthiophene) (P3HT):phenyl?C 61 ?butyric acid methyl ester (PC 61 BM) under identical conditions. Corresponding increases in short?circuit current density ( J sc ), open?circuit voltage ( V oc ), fill factor (FF), and incident photon?to?current efficiency (IPCE) enable 31% PCE improvement due to the enhancement of the light?trapping and the improvement of charge transport in the active layer. The findings advance the fundamental understanding and point to the superiority of Au 11 Ag 89 nanoalloys as a promising metallic additive over Au, Ag, and Au 28 Ag 72 alloy NPs to boost the solar cell performance.
SDGs
Type
journal article