Renormalization effects of bath-induced vibronic population transfer on stationary and time-resolved resonant light scattering spectra from molecules
Journal
The Journal of Chemical Physics
Journal Volume
93
Journal Issue
1
Pages
126-135
Date Issued
1990
Author(s)
Abstract
Renormalization effects of the bath-induced vibronic population transfer on resonant light scattering (RLS) from molecules in condensed phases are theoretically studied based on the Markoffian master equation approach. By using the double space diagram technique, the self-energy originated from the bath-induced vibronic population transfer is analytically solved, and the analytic expressions for the intensities both of the stationary and of the time-resolved RLS spectra are derived. The renormalization effect is analyzed in terms of dimensionless molecular parameters, and model calculations are also performed to confirm theoretical results.
Type
journal article